Chemistry Semester 1 Final


  1. The measurement, 0.034050 cm, has how many significant digits?

    3

    4

    5

    6

    7


  2. Perform the following using the rules for significant figures: 30.55 + 2.7 =

    33

    33.2

    33.3

    33.25

    33.2500


  3. Perform the following calculation using the rules for significant figures: 3.050 X 150 = ?

    500

    460

    458

    547.5

    547.50


  4. If you wish to calculate the number of miles in two inches, what would be wrong with calculation:

    1 foot does not equal 12 inches.

    1 mile does not equal 5280 feet.

    The second fraction is upside down.

    The third fraction is upside down.

    The calculation is correct.


  5. What is the best name for FeCl3?

    Iron Trichloride

    Iron Chloride

    Iron (III) Chloride

    Iron (III) Trichloride

    Ferric Trichloride


  6. What is the molecular weight of Cu(NO3)2?

    93.5 g/mol

    125.5 g/mol

    173.5 g/mol

    187.5 g/mol

    251 g/mol


  7. How many moles are there in 10.0 g of water?

    0.555 mol

    1.8 mol

    10. mol

    28 mol

    180 mol


  8. How many atoms are in 0.05 mol of Al?

    8 x 10 -26

    3 x 10 22

    8 x 10 23

    1 x 10 21

    3 x 10 23


  9. What would be the mass of one helium atom?

    4 g

    7 x 10 -24 g

    2 x 10 24 g

    4 x 10 -25 g

    1.5 x 10 23 g


  10. The mass of a container of oxygen gas (O2) has a mass of 2.00 g. An equally sized container at the same temperature and pressure would contain how many grams of carbon dioxide (CO2)?

    0.364 g

    1.45 g

    0.688 g

    2.75 g

    5.50 g


  11. The reaction N2 + 3 H2 2 NH3 cannot be interpretted as:

    1 molecule of N2 reacts with 3 molecules of H2 to produce 2 molecules of NH3.

    1 mole of N2 reacts with 3 moles of H2 to produce 2 moles of NH3.

    1 liter of N2 gas reacts with 3 liters of H2 gas to produce 2 liters of NH3 gas.

    2 atoms of N react with 6 atoms of H to produce 2 atoms of N and 6 atoms of H.

    1 gram N2 reacts with 3 grams of H2 to produce 2 grams of NH3.


  12. What coefficients (listed in order) should be used to balance the following reaction?

    ___ C2H6 + ___ O2 ___ CO2 + ___ H2O

    1, 3, 2, 3

    1, 3.5, 2, 3

    2, 7, 2, 6

    2, 7, 6, 4

    1, 3, 3, 3


  13. In the reaction, N2 + 3 H2 2 NH3, 1.0 mole of N2 could produce how many grams of NH3?

    2

    8.5

    17

    34

    None of these.


  14. In the reaction, N2 + 3 H2 2 NH3, 5.0 g of N2 could produce how many grams of NH3?

    0.011

    2.1

    3.0

    12

    None of these.


  15. In the reaction, N2 + 3 H2 2 NH3, 2 grams of H2 of could produce how many molecules of NH3?

    4 x 10 23

    9 x 10 23

    2 x 10 24

    1 x 10 23

    None of these.


  16. In the reaction, N2 + 3 H2 2 NH3, how many moles of NH3 could be formed when 2.0 moles of N2 reacted with 2 moles of H2?

    2.0

    1.3

    2.3

    4.0

    None of these.


  17. Standard Temperature and Pressure (STP) refers to which of the following conditions:

    Temp = 0 K; Press = 760 atm

    Temp = 0 oC; Press = 760 atm

    Temp = 273 K; Press = 1 atm

    Temp = 273 oC; Press = 1 atm

    STP conditions are NOT listed above


  18. Of the following, which would NOT increase the volume of a balloon full of air.

    Increase the temperature of the air inside the balloon.

    Increase the amount of air inside the balloon.

    Replace the air inside the balloon with the same number of molecules of a higher molecular weight gas.

    Decrease the atmospheric pressure outside the balloon.

    Increase the speeds of the molecules inside the balloon.


  19. If pressure were plotted on the "Y" axis and volume were plotted on the "X" axis, which graph would properly illustrate the relationship between the pressure and volume of a gas?


  20. A 2.0 L sample of a gas at 25 oC had its temperature increased to 50 oC. What would be the new volume of the gas? (Remember V1P1/T1 = V2P2/T2.)

    40.0 L

    0.25 L

    48,000 L

    0.000021 L

    2.2 L


  21. How many liters of a gas are present at STP in a sample which occupies 2.05 liters at 3.0 atm pressure and 27 oC? (Remember V1P1/T1 = V2P2/T2.)

    0.23

    5.6

    6.8

    5.0 x 105

    1.3


  22. In the reaction, N2 + 3 H2 2 NH3, 2.00 liters of N2 at STP would require how many grams of H2 to react completely? (At STP 1 mole of a gas = 22.4 L)

    0.536 g

    0.0595 g

    0.268 g

    269 g

    29.9 g


  23. The graph at right illustrates shows the distributions of speeds of a gas sample at two different temperatures. Which of the following is a correct interpretation of the graph:

    B has more molecules than A

    The average molecular speed of A is greater than B.

    The average molecular speed of B is greater than A.

    Both A and B are correct.

    Both A and C are correct.


  24. The graph at right shows a solid warmed until it changes to a gas. During what section(s) is a liquid present?

    Section B

    Section C

    Section D

    Sections B, C, and D

    None of the above.


  25. Use the graph in question 24 to indicate the section(s) where the kinetic energy of the molecules is increasing.

    Section C

    Section D

    Sections B and D

    Sections A, C, and E

    None of the above.


  26. What would you use to calculate energy changes in section C of the graph in question 24?

    The heat of fusion of the substance.

    The specific heat of the substance.

    The heat of vaporization of the substance.

    The heat of reaction of the substance.

    None of the above.


  27. If it requires 100. calories to increase the temperature of 5.00 g of a substance 15.0 oC, what is the specific heat of the substance?

    7500 cal / (g oC)

    300 cal / (g oC)

    33.3 cal / (g oC)

    0.750 cal / (g oC)

    None of the above.


  28. How much energy would it require to completely melt 25.0 g of ice at 0 oC? (The heat of fusion of water is 1.44 Kcal/mol.)

    36.0 Kcal

    2.00 Kcal

    648 Kcal

    313 Kcal

    None of the above.


  29. The graph at right indicates the vapor pressure of different substances as the temperature increases. What is the normal boiling point of chloroform?

    20 oC

    40 oC

    60 oC

    80 oC

    None of the above.


  30. Use the graph in question 29 to decide at what temperature water would boil if atmospheric pressure was 40 KPa.

    100 oC

    10 oC

    73 oC

    35 oC

    None of the above.


  31. Which of the substances in the graph in question 29 would have the lowest heat of vaporization?

    Chloroform

    Ethanol

    Water

    Ethanoic Acid

    It is impossible to tell.


  32. As more solute is added to a solution, the boiling point tends to _____.

    increase

    decrease

    remain unchanged

    It is impossible to predict.


  33. If 10.0 g of NaCl are dissolved in enough water to make 250. mL of solution, what is the molarity of the solution?

    0.000584 M

    0.684 M

    0.0437 M

    2340 M

    0.00684 M


  34. In the reaction, CaCO3 + HCl CO2 + CaCl2 + H2O, 25 mL of 2.0 M HCl would react with how many grams of CaCO3? (Hint: Do not forget to balance the reaction.)

    10. g

    5.0 g

    25 g

    2.5 g

    None of the above.


  35. The graph at right shows the solubility of a solid when dissolved in 100 g of water to make a solution. How much solid would have to be dissolved in 100 g of water to make a saturated solution at 60 oC?

    80 g

    25 g

    120 g

    90 g

    It is impossible to tell.


  36. Use the graph in question 35 to determine how many grams of the solute would remain at the bottom a beaker if you attempted to dissolve 40 g of the solute in 100 g of water at 20 oC.

    All 40 grams would dissolve.

    About 5 grams of solute would remain at the bottom of the beaker.

    About 10 grams of solute would remain at the bottom of the beaker.

    About 23 grams of solute would remain at the bottom of the beaker.

    About 30 grams of solute would remain at the bottom of the beaker.


  37. Use your table of solubilities to decide which of the substances below is soluble:

    Ca3(PO4)2

    AgCH3COO

    PbSO4

    BaCrO4

    None of the above are soluble.


  38. Which of the dissolution reactions below is correct?

    NaHCO3 Na+ + HCO3-

    K2SO4 K2+2 + SO42-

    HNO3 H- + NO3+

    Ca(NO3)2 Ca2+ + (NO3-)2

    None of the above are correct.


  39. Which of the following shows a correct ionic equation? (Use your table of solubilities.)

    Pb2+ + 2 NO3- + 2 K+ + SO42- PBK2 (s) + 2 NO3- + SO42-

    Pb2+ + 2 NO3- + 2 K+ + SO42- PbSO4 (s) + 2 K+ + 2 NO3-

    Pb2+ + 2 NO3- + 2 K+ + SO42- (NO3)2SO4 (s) + Pb2+ + 2 K+

    Pb2+ + 2 NO3- + 2 K+ + SO42- 2 KNO3 (s) + Pb2+ + SO42-

    None of these is correct.


  40. Use the periodic table to predict which of the following compounds is possible:

    NaNe

    CaI3

    AlO2

    K2S

    None of the above are correct.


  41. Which of the following statements about the horizontal rows of the elements in the periodic table is TRUE?

    From left to right the atomic numbers tend decrease.

    From left to right the atomic masses tend to decrease.

    From left to right the atomic radii tend to decrease.

    From left to right the ionization energies tend to decrease.

    None of the above are correct.


  42. The properties of what element are described in the following sentences?

    1. It is a gas at room temperature.
    2. It forms a diatomic molecule.
    3. It forms a +1 ion.

    Br

    Li

    H

    Xe

    Cl


  43. The properties of what element are described in the following sentences?

    1. It reacts with Hydrogen in a 1:1 ratio.
    2. It is a liquid at room temperature.
    3. It forms a -1 ion.

    Br

    Li

    H

    Xe

    Cl


  44. Using the periodic table, pick the pair of atoms that would most likely form a molecular compound.

    H and Cl

    Li and Br

    Na and O

    He and Ne

    Cl and Cl


  45. Which one of the following statements about elements in the first column of the periodic table is TRUE?

    These elements are called halogens.

    These elements have the smallest atoms in their period.

    These elements have the smallest ionizations energies in thier period.

    These elements are not very reactive with water.

    None of these statements are true.


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